石油沥青基炭材料电化学储能应用综述

A review of petroleum asphalt-based carbon materials in electrochemical energy storage

  • 摘要: 石油沥青是石油化工行业中一类重要的副产品,用途广泛但工业附加值往往较低。由于石油沥青具有成本低、炭含量高且富含多环芳烃等特点,对其进行改性和结构设计可以提高其价值,并扩展其储能应用。选择石油沥青作为前驱体并采用精细化的设计策略,有望解决因额外添加模板或活化剂而导致的环境问题、设备维护难题和生产水平低的问题。本文综述了当前石油沥青基炭材料的常用制备方法,包括模板辅助热解、熔盐、活化、杂原子掺杂和预氧化的研究进展,还介绍了其在超级电容器和碱金属离子电池等电化学储能装置中的应用。此外,归纳提出了未来研究中可能面临的挑战,并提出了相应的解决策略,旨在为石油沥青的高附加值利用提供新的视角和思路。

     

    Abstract: Petroleum asphalt, an important by-product of the petrochemical industry, has diverse applications but often suffers from low industrial added value. Because of its low cost, high carbon content, and high polycyclic aromatic hydrocarbon content, appropriate modification can increase its value and expand its energy storage applications. Current research progress on the common preparation methods of petroleum asphalt-based carbon materials, including template-assisted pyrolysis, molten salt treatment, activation, heteroatom doping, and pre-oxidation is reviewed, and its use in supercapacitors and alkali metal ion batteries, is also elaborated. Feasible solutions for the current problems with petroleum asphalt are proposed, with the aim of providing insights into its high value-added utilization.

     

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