炭材料在柔性锌离子电池中的研究进展

Recent advances in carbon materials for flexible zinc ion batteries

  • 摘要: 近年来,随着智能可穿戴设备市场的不断增长,柔性储能器件的设计和开发得到了快速发展。水系锌离子电池(ZIBs)具有成本低、高安全等优势,得到了广泛研究。炭材料具有质轻、高导电与柔性等特点,在构筑高性能柔性锌离子电池(FZIBs)方面具有诸多优势。本文详细总结了炭材料(碳纳米管、炭纤维、石墨烯)在一维线状、二维平面、三维三明治构型FZIBs中的研究进展,着重强调了炭材料构筑FZIBs的策略,系统归纳了炭材料在正极、负极和隔膜中的角色,重点强调了炭材料对FZIBs的性能增强作用。最后,简要讨论了先进炭材料在下一代柔性锌离子电池中的挑战和前景。

     

    Abstract: The ever-growing demands for wearable devices has stimulated the development of advanced flexible energy storage devices. Aqueous rechargeable zinc ion batteries (ZIBs) have gained much attention due to their low cost and intrinsic safety. Carbon materials with excellent conductivity, high mechanical strength, and light weight, can be used to construct flexible ZIBs (FZIBs). Here, we summarize the recent advances in carbon materials (e.g., carbon nanotubes, carbon fibers, graphene) for high-performance FZIBs with one-dimensional cable-shaped, two-dimensional planar, and three-dimensional sandwich configurations. Ways for constructing different types of FZIBs for better electrochemical performance are emphasized. The vital roles of carbons as the conductive materials and current collectors of cathodes, the current collectors and host materials of anodes, and modifiers of functional separators are discussed. The challenges and prospects of advanced carbon materials for next-generation FZIBs are also briefly discussed.

     

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