李国华, 王静, 任锦添, 刘洪辰, 钱锦绣, 程佳婷, 赵美彤, 杨帆, 李永峰. 碳组分对碳基过渡金属电解水析氢催化剂性能影响的总结[J]. 新型炭材料. DOI: 10.1016/S1872-5805(24)60880-2
引用本文: 李国华, 王静, 任锦添, 刘洪辰, 钱锦绣, 程佳婷, 赵美彤, 杨帆, 李永峰. 碳组分对碳基过渡金属电解水析氢催化剂性能影响的总结[J]. 新型炭材料. DOI: 10.1016/S1872-5805(24)60880-2
LI Guo-hua, WANG Jing, REN Jin-tian, LIU Hong-chen, QIAN Jin-xiu, CHENG Jia-ting, ZHAO Mei-tong, YANG Fan, LI Yong-feng. A review for the effect of carbon components on the performance of carbon-based transition metal electrocatalysts for hydrogen evolution reaction[J]. New Carbon Mater.. DOI: 10.1016/S1872-5805(24)60880-2
Citation: LI Guo-hua, WANG Jing, REN Jin-tian, LIU Hong-chen, QIAN Jin-xiu, CHENG Jia-ting, ZHAO Mei-tong, YANG Fan, LI Yong-feng. A review for the effect of carbon components on the performance of carbon-based transition metal electrocatalysts for hydrogen evolution reaction[J]. New Carbon Mater.. DOI: 10.1016/S1872-5805(24)60880-2

碳组分对碳基过渡金属电解水析氢催化剂性能影响的总结

A review for the effect of carbon components on the performance of carbon-based transition metal electrocatalysts for hydrogen evolution reaction

  • 摘要: 析氢反应被认为是最有前途的制氢技术。开发具有优异电化学性能的非贵金属材料对促进电催化的实际应用至关重要。碳基过渡金属催化剂具有较高的活性和稳定性,对降低氢气生产成本和促进氢气工业的发展具有重要意义。然而,关于碳组分对碳基过渡金属电催化剂性能的影响,缺乏相关报道。因此,我们总结了与电解水析氢有关的过渡金属/碳的文献,讨论了复合结构中碳组分的设计策略及其对催化性能的影响,包括杂原子掺杂的电子结构调整、形貌调整、以及自支撑材料对碳基过渡金属催化剂的影响。这篇综述不仅分析了电解水析氢反应的进展,而且为指导高性能碳基过渡金属催化剂的合成提供了见解。

     

    Abstract: Hydrogen evolution reaction is a promising way to produce hydrogen. Exploiting non-precious metals with excellent electrochemical performance is vital to promoting the practical application of electrocatalysis. Carbon-based transition metal catalysts have high activity and stability, which are important in reducing the cost of hydrogen production and promoting the development of the hydrogen production industry. However, there is a lack of relevant discussion regarding the effect of carbon components on the performance of carbon-based transition metal electrocatalysts. Herein, we fill this gap by summarizing the literature on carbon-based transition metal electrocatalysts pertaining to hydrogen evolution reaction, discussing the design strategies of carbon components in composite structures and their impact on catalytic performance, including electronic structure control by heteroatom doping, morphology adjustment, and the influence of self-supporting materials on carbon-based transition metal catalysts. This review not only analyzes the progress in hydrogen evolution reaction, but also provides valuable guidance for synthesizing high-performance carbon-based transition metal catalysts.

     

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