牵伸石墨化对石墨纤维结构和力学性能的影响

牵伸石墨化对石墨纤维结构和力学性能的影响

  • 摘要: 借助XRD和力学测试研究了不同石墨化温度下牵伸率(0%~2.5%)对PAN基石墨纤维结构和力学性能的影响。结果表明:在2400℃、2700℃和3000℃石墨化温度下,分别采用1.25%,1.50%和2.20%的牵伸率,可获得的抗拉强度最大值相应为3.1GPa、2.55GPa和2.25GPa。在相同的石墨化温度下与未牵伸的样品相比,抗拉强度提高了10%~20%。弹性模量亦随牵伸率的增大而增加,在牵伸率为2.50%时,弹性模量上升15%。同时,石墨微晶尺寸Lc(3.612nm~7.094nm)和La(12.909nm~24.400nm)及取向度逐渐增大,而d002(0.3465nm~0.3418nm)逐渐减小。微观结构的改善是石墨纤维抗拉强度和弹性模量提高的主要原因。

     

    Abstract: The influence of stretching ratio between 02.5% on microstructure and mechanical properties of PANbased graphite fibers was investigated by XRD and mechanical testing for graphitization temperatures of 2400, 2700 and 3000℃. Results show that stretching ratios of 1.25, 1.5 and 2.20% yield a maximum tensile strength of 3.1, 2.55 and 2.25GPa at 2400, 2700 and 3000℃ respectively, and the maximum tensile strength is an increase of about 10-20% compared to the unstretched samples at the same temperature. The elasticity modulus of the graphite fibers increases with stretching ratio at the different temperatures investigated and is 15% larger than that of the unstretched samples at a stretching ratio of 2.5%. The size of crystallites Lc (3.612-7.094nm), La (12.90924.400nm) and orientation degree of crystallites (89.51-92.97%) increase, but d002 (0.3465-0.3418nm) decreases with the stretching. This contributes to the increase of tensile strength and modulus of the graphite fibers.

     

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