由柏木制备纳米孔结构炭材料I.制备与孔结构(英文)

由柏木制备纳米孔结构炭材料I.制备与孔结构(英文)

  • 摘要: 柏木条经过热蒸气处理,成功地制备了纳米孔炭,无需另行活化,比表面积就可达1000m2/g以上。如果在800℃~870℃炭化,柏木炭外表面积可达400m2/g以上,与同样温度在氩气中炭化得到的柏木炭相比,后者微孔面积仅为30m2/g~40m2/g。在900℃以上炭化得到的柏木炭,微孔表面积高达800m2/g以上,外表面积约为150m2/g。柏木炭的孔结构可以通过调节过热蒸气的温度得到控制。

     

    Abstract: Nanoporous carbons were prepared from cypress chips under a flow of superheated steam, and their surface area reached more than 1000m2/g without an additional activation process. Cypress charcoals prepared at a temperature of 800-870℃ had a large external surface area of more than 400m2/g, comparable to the microporous surface area, even though only 30-40m2/g was obtained by carbonization in a flow of Ar gas. Cypress charcoals prepared above 900℃ were microporous with a microporous surface area more than 800m2/g and an external surface area of about 150m2/g. The pore structure in cypress charcoals could be controlled by selecting the temperature of the steam.

     

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