硝酸氧化改性SBA-15 模板合成的中孔炭电容性能研究(英文)

硝酸氧化改性SBA-15 模板合成的中孔炭电容性能研究(英文)

  • 摘要: 采用有序中孔氧化硅SBA-15为模板,合成了具有高效能量存储的超级电容器电极材料——有序中孔炭材料;以硝酸为氧化剂,分别在26℃、50℃、70℃和100℃下对中孔炭进行了表面官能化处理。结合氮气等温吸附、X射线光电子能谱和热分析方法研究了氧化前后中孔炭孔结构和表面官能团的演化。结果表明:随着氧化温度的升高,比表面积和中孔含量减少,而表面官能团含量增加。电化学测试显示:原始中孔炭的能量密度为3.5Wh/kg,100℃氧化的中孔炭具有最高的能量密度(5.7Wh/kg)。表明硝酸官能化处理可将中孔炭材料应用范围拓展到高能量密度领域。同时初始中孔炭的功率密度为2015W/kg,70℃氧化的中孔炭具有最高的功率密度(3125W/kg)。研究表明能量密度的改善得益于表面官能化对双电层电荷密度的提高和引入了法拉第赝电容反应;而功率密度的提高来自亲水性的官能化炭表面所具有的低离子扩散阻力。

     

    Abstract: This study reports modified SBA15 templated mesoporous carbon as a supercapacitor electrode for highefficiency energy storage. Mesoporous carbon was oxidized in concentrated nitric acid at 26℃, 50℃, 70℃, and 100℃. The evolution of mesopores and surface oxygencontaining functional groups (SOFGs) of the mesoporous carbons were studied by nitrogen cryosorption, Xray photoelectron spectroscopy, and thermogravimetric analysis. The results demonstrate that the specific surface area and the mesopore volume decrease, while the SOFGs accumulate with increasing oxidation temperature. The supercapacitor performance was characterized in a KOH aqueous electrolyte. An enhanced energy density with a highest value of 5.7Wh/kg is obtained after oxidation at 100℃ compared to 3.5Wh/kg before oxidation, demonstrating the possibility of using modified mesoporous carbons in high energy density applications. The enhanced energy density is attributed to the contribution of SOFGs to charge storage in both the electric double layer and the Faradic reaction. The power density is also improved with a highest value of 3125W/kg after oxidation at 70℃ compared to the original value of 2015W/kg. The improvement of power density relies on the improved wettability of carbon surfaces, which can facilitate the ion transport.

     

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