等离子喷涂法制备炭/炭复合材料硅酸钇涂层研究

Yttrium silicate coatings for SiC coated C/C composites prepared by atmospheric plasma spraying

  • 摘要: 采用等离子喷涂(Atmospheric plasma spraying , APS)法在炭/炭复合材料碳化硅(SiC)内涂层表面制备了硅酸钇涂层。分别采用XRD和SEM分析了所得涂层的微观结构,并测试了带有SiC/硅酸钇复合涂层的炭/炭复合材料试样在1500℃静态空气中的抗氧化性能。结果表明:通过调节喷涂粉料中的SiO2和Y2O3的摩尔比,可制得Y2SiO5、Y2Si2O7、Y2Si2O7/Y2SiO5和Y4Si3O12/Y2Si2O7/ Y2SiO5四种不同结构的硅酸钇涂层;1500℃氧化73h后,SiC/Y4Si3O12/Y2Si2O7/Y2SiO5涂层试样的氧化失重速率相对较低,仅为1.01×10-4 g · cm-2 · h-1

     

    Abstract: Different yttrium silicate coatings for SiC-coated C/C composites were designed and prepared by an atmospheric plasma spray method to prevent the C/C composites from oxidation. XRD profiles showed that the coating was composed of Y2SiO5, Y2Si2O7, and Y4Si3O12. SEM showed that the gradient SiC/Y4Si3O12/Y2Si2O7/Y2SiO5 coating had a more compact surface than the other coatings did. Isothermal oxidation tests at 1500℃ in air showed that the weight loss curves of the as-prepared C/C composites showed a linear tendency with time and the weight loss rate of all coated samples increased significantly after 73h. The coating could protect the C/C composites from oxidation at 1500℃ for 73h in air with a weight loss rate of 1.01×10-4g · cm-2 · h-1. The SiC/Y4Si3O12/Y2Si2O7/Y2SiO5 was the better coating at high temperature than other coatings.

     

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