热处理温度对聚酰亚胺基炭纤维结构性能影响

Effect of heat treatment temperature on the microstructure and properties of polyimide-based carbon fibers

  • 摘要: 以聚酰亚胺(PI)纤维为前驱体,经 800 ~2800°C连续高温处理,制备出不同性能的聚酰亚胺基炭(石墨)纤维。 采用元素分析、SEM、HR-TEM、Raman、纤维强力仪、电阻率仪等分析手段研究热处理温度对炭纤维(CF)元素含量、结构形貌、力学性能、传导性能等方面的影响。 结果表明,随着热处理温度的升高,聚酰亚胺基炭纤维中碳含量从78. 97% (800°C)提高到 99. 72% (2800°C),非碳原子含量降低;聚酰亚胺基炭纤维表面缺陷数目增加且尺寸增大。 同时,纤维的微观结构也从二维乱层石墨结构向有序的三维层状结构发展,表现为石墨化程度的提高及石墨微晶尺寸的增大;炭纤维拉伸强度先增加后降低,最大拉伸强度 924. 4 MPa, 断裂伸长率降低, 电阻率减小, 热导率增加,2 800 °C 石墨化处理后纤维热导率为 228. 4 W · m -1 · K -1 ,是 800°C处理后的 50. 4 倍。

     

    Abstract: Polyimide(PI)-based carbon fibers with different properties were prepared by carbonization of PI fibers at 800°C Polyimide(PI)-based carbon fibers with different properties were prepared by carbonization of PI fibers at 800°C, followed by heat treatment from 800 to 2 800°C. The effect of heat treatment temperature (HTT) on elemental composition, surface morphology, mechanical properties, and the thermal and electrical conductivities of PI-based carbon fibers were investigated by elemental analysis, SEM, HRTEM, Raman spectroscopy, mechanical testing, and electrical and thermal conductivity measurements. Results showed that as a result of HTT the carbon content increased from 78. 97% to 99. 72%, the tensile strength exhibited a maximum of 924. 4 MPa, and the degree of graphitization and the size of graphite crystallites were both increased. Distinct reductions in strain-to-failure and electrical resistivity were observed with increasing HTT. The thermal conductivity can reach 228. 4 W · m -1 · K -1 after heat treatment at 2 800 °C. PI fiber may be a good precursor for carbon fibers with a high thermal conductivity. Polyimide(PI)-based carbon fibers with different properties were prepared by carbonization of PI fibers at 800 Polyimide(PI)-based carbon fibers with different properties were prepared by carbonization of PI fibers at 800°C Polyimide(PI)-based carbon fibers with different properties were prepared by carbonization of PI fibers at 800°C, followed by heat treatment from 800 to 2 800°C. The effect of heat treatment temperature (HTT) on elemental composition, surface morphology, mechanical properties, and the thermal and electrical conductivities of PI-based carbon fibers were investigated by elemental analysis, SEM, HRTEM, Raman spectroscopy, mechanical testing, and electrical and thermal conductivity measurements.
    Results showed that as a result of HTT the carbon content increased from 78. 97% to 99. 72%, the tensile strength exhibited a maximum of 924. 4 MPa, and the degree of graphitization and the size of graphite crystallites were both increased. Distinct reductions in strain-to-failure and electrical resistivity were observed with increasing HTT. The thermal conductivity can reach 228. 4 W · m -1 · K -1
    after heat treatment at 2 800 °C. PI fiber may be a good precursor for carbon fibers with a high thermal conductivity. Polyimide(PI)-based carbon fibers with different properties were prepared by carbonization of PI fibers at 800°C, followed by heat treatment from 800 to 2 800 °C. The effect of heat treatment temperature (HTT) on elemental composition, surface morphology, mechanical properties, and the thermal and electrical conductivities of PI-based carbon fibers were investigated by elemental analysis, SEM, HRTEM, Raman spectroscopy, mechanical testing, and electrical and thermal conductivity measurements.Results showed that as a result of HTT the carbon content increased from 78. 97% to 99. 72%, the tensile strength exhibited a maximum of 924. 4 MPa, and the degree of graphitization and the size of graphite crystallites were both increased. Distinct reductions in strain-to-failure and electrical resistivity were observed with increasing HTT. The thermal conductivity can reach 228. 4 W · m -1 · K -1 after heat treatment at 2 800°C. PI fiber may be a good precursor for carbon fibers with a high thermal conductivity., followed by heat treatment from 800 to 2 800°C. The effect of heat treatment temperature (HTT) on elemental composition, surface morphology, mechanical properties, and the thermal and electrical conductivities of PI-based carbon fibers were investigated by elemental analysis, SEM, HRTEM, Raman spectroscopy, mechanical testing, and electrical and thermal conductivity measurements. Results showed that as a result of HTT the carbon content increased from 78. 97% to 99. 72%, the tensile strength exhibited a maximum of 924. 4 MPa, and the degree of graphitization and the size of graphite crystallites were both increased. Distinct reductions in strain-to-failure and electrical resistivity were observed with increasing HTT. The thermal conductivity can reach 228. 4 W · m -1 · K -1 after heat treatment at 2 800 °C. PI fiber may be a good precursor for carbon fibers with a high thermal conductivity, followed by heat treatment from 800 to 2 800 °C. The effect of heat treatment temperature (HTT) on elemental composition, surface morphology, mechanical properties, and the thermal and electrical conductivities of PI-based carbon fibers were investigated by elemental analysis, SEM, HRTEM, Raman spectroscopy, mechanical testing, and electrical and thermal conductivity measurements. Results showed that as a result of HTT the carbon content increased from 78. 97% to 99. 72%, the tensile strength exhibited a maximum of 924. 4 MPa, and the degree of graphitization and the size of graphite crystallites were both increased. Distinct reductions in strain-to-failure and electrical resistivity were observed with increasing HTT. The thermal conductivity can reach 228. 4 W · m -1 ·  K -1 after heat treatment at 2 800°C. PI fiber may be a good precursor for carbon fibers with a high thermal conductivity., followed by heat treatment from 800 to 2 800°C  . The effect of heat treatment temperature (HTT) on elemental composition, surface morphology, mechanical properties, and the thermal and electrical conductivities of PI-based carbon fibers were investigated by elemental analysis, SEM, HRTEM, Raman spectroscopy, mechanical testing, and electrical and thermal conductivity measurements. Results showed that as a result of HTT the carbon content increased from 78. 97% to 99. 72%, the tensile strength exhibited a maxi mum of 924. 4 MPa, and the degree of graphitization and the size of graphite crystallites were both increased. Distinct reductions in strain-to-failure and electrical resistivity were observed with increasing HTT. The thermal conductivity can reach 228. 4 W · m -1 · K -1 after heat treatment at 2 800°C. PI fiber may be a good precursor for carbon fibers with a high thermal conductivity.

     

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