气相原位聚合制备碳纳米管/乙丙橡胶复合材料及其性能表征

Properties of carbon nanotube/ethylene-propylene rubber composites prepared by an in-situ gas phase polymerization method

  • 摘要: 以碳纳米管为防黏助剂,通过气相原位聚合制备了乙丙橡胶复合材料。加入适量的碳纳米管可以防止聚合过程中由于温度升高导致的橡胶颗粒软化粘结问题,且碳纳米管的加入对乙丙橡胶的熔融温度和热解温度没有影响;与导电炭黑相比,碳纳米管的加入显著提高了复合材料的导电性能和拉伸强度;通过气相原位聚合制备的复合材料,碳纳米管在乙丙橡胶中的分散良好,其导电性能优于机械共混法制备的碳纳米管-橡胶复合材料。

     

    Abstract: Carbon nanotube/ethylene-propylene rubber composites were prepared by gas-phase polymerization of the monomers in an autoclave loaded with carbon nanotubes under agitation. The aggregation of rubber particles during polymerization was effectively prevented by adding more than 6.76 wt% carbon nanotubes that were well dispersed in the composites. The addition of carbon nanotubes had no effect on the melting and thermal decomposition temperatures of the rubber. The composites with carbon nanotubes had a significantly better conductivity and tensile strength than those with conductive carbon black or those obtained with the same formulations using a mechanical blending method.

     

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