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The production of electrodes for microsupercapacitors based on MoS2-modified reduced graphene oxide aerogels by 3D printing

WANG Meng-ya LI Shi-you GAO Can-kun FAN Xiao-qi QUAN Yin LI Xiao-hua LI Chun-lei ZHANG Ning-shuang

王梦雅, 李世友, 高灿坤, 樊晓琦, 权银, 李小华, 李春雷, 张宁霜. 以MoS2修饰的3D打印还原石墨烯气凝胶制备微型超级电容器电极. 新型炭材料(中英文), 2024, 39(2): 283-296. doi: 10.1016/S1872-5805(24)60823-1
引用本文: 王梦雅, 李世友, 高灿坤, 樊晓琦, 权银, 李小华, 李春雷, 张宁霜. 以MoS2修饰的3D打印还原石墨烯气凝胶制备微型超级电容器电极. 新型炭材料(中英文), 2024, 39(2): 283-296. doi: 10.1016/S1872-5805(24)60823-1
WANG Meng-ya, LI Shi-you, GAO Can-kun, FAN Xiao-qi, QUAN Yin, LI Xiao-hua, LI Chun-lei, ZHANG Ning-shuang. The production of electrodes for microsupercapacitors based on MoS2-modified reduced graphene oxide aerogels by 3D printing. New Carbon Mater., 2024, 39(2): 283-296. doi: 10.1016/S1872-5805(24)60823-1
Citation: WANG Meng-ya, LI Shi-you, GAO Can-kun, FAN Xiao-qi, QUAN Yin, LI Xiao-hua, LI Chun-lei, ZHANG Ning-shuang. The production of electrodes for microsupercapacitors based on MoS2-modified reduced graphene oxide aerogels by 3D printing. New Carbon Mater., 2024, 39(2): 283-296. doi: 10.1016/S1872-5805(24)60823-1

以MoS2修饰的3D打印还原石墨烯气凝胶制备微型超级电容器电极

doi: 10.1016/S1872-5805(24)60823-1
基金项目: 甘肃省重点研发计划(21YF5GA079);兰州理工大学红柳一流学科建设计划
详细信息
    通讯作者:

    张宁霜,博士,副教授. E-mail:zhangns@lut.edu.cn

  • 中图分类号: TQ127.1+1

The production of electrodes for microsupercapacitors based on MoS2-modified reduced graphene oxide aerogels by 3D printing

Funds: This work was supported by the Key R&D plan of Gansu Province (21YF5GA079) and the Lanzhou University of Technology Hongliu First-class Discipline Construction Program
More Information
  • 摘要: 微型超级电容器(MSCs)具有高的功率密度和卓越的循环性能,广泛的潜在应用,因而受到诸多关注。然而,制备具有高表面电容和能量密度的MSCs电极仍然存在挑战。本研究使用还原石墨烯气凝胶(GA)和二硫化钼(MoS2)作为材料,结合3D打印和表面修饰方法成功构建了具有超高表面电容和能量密度的MSCs电极。通过3D打印技术,获得具有稳定宏观结构和GA交联微孔结构的电极。此外,采用溶液法在3D打印电极表面加载MoS2纳米片,进一步提高了材料的电化学性能。具体而言,电极的表面电容达3.99 F cm−2,功率密度为194 µW cm−2,能量密度为1997 mWh cm−2,表现出卓越的电化学性能和循环稳定性。这项研究为制备具有高表面电容和高能量密度的微型超级电容器电极提供了一种简单高效的方法,在MSCs电极领域具有重要的参考意义。
  • FIG. 3063.  FIG. 3063.

    FIG. 3063..  FIG. 3063.

    Figure  1.  Procedure of the overall printing scheme, loading engineering, and structure of an assembled device

    Figure  2.  (a) SEM image and (b) TEM image of GO, (d) SEM image and (e) TEM image of GA, (c, f) SEM images at different magnifications of the 3DPE framework sample

    Figure  3.  Rheological properties of the formulated ink in (a) viscosity versus shearing rate and (b) storage and loss modulus versus shear stress. (c) Raman spectra of raw materials GO and GA. (d) Diffraction XRD patterns collected in 2θ scan of GO, GA and 3DPE. XPS high-resolution scans of C 1s (e) GO, (f) GA and (g) 3DPE

    Figure  4.  (a) The galvanostatic charge-discharge curves at a current density of 1 A g−1 and (b) the cycling voltammetry curves at a scanning rate of 10 mV s−1 of 3DPE with different layers. (c) The areal and (d) gravimetric capacities at different current densities of 3DPE with different layers. (e) The areal and (f) gravimetric capacities at a current density of 1 A g−1 of 3DPE with different layers. (g) Impedance nyquist plots of 3DPE with different layers. (h) Cycling stability of 3DPE-4 at a current density of 1 A g−1

    Figure  5.  (a) SEM image, (b) TEM image and (c) EDX mapping of the Mo-3DPE

    Figure  6.  (a) Raman spectra, (b) XRD of 3DPE and Mo-3DPE, (c) XPS high-resolution scans of S 2p of Mo-3DPE, (d) XPS high-resolution scans of Mo 3d of MoS2 and (e) XPS high-resolution scans of Mo 3d of Mo-3DPE

    Figure  7.  (a) The gravimetric and (b) areal capacities of 3DPE-4 and Mo-3DPE-4 at a current density of 1 A g−1. (c) The cycling voltammetry curves at a scanning rate of 10 mV s−1 and (d) the galvanostatic charge-discharge curves of 3DPE-4 and Mo-3DPE-4 at a current density of 1 A g−1. (e) Impedance Nyquist plots of 3DPE-4 and Mo-3DPE-4. (f) The contribution of Mo-3DPE at different scan rates. (g) Cycling stability of Mo-3DPE-4 at a current density of 1 A g−1

    Figure  8.  (a) Ragone plots[8,25,38,44-46]. (b) Comparison of the areal capacitance and gravimetric areal energy density in this work with those in other works[3,29,36,44-46].

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出版历程
  • 收稿日期:  2023-08-05
  • 录用日期:  2023-11-10
  • 修回日期:  2023-11-09
  • 网络出版日期:  2023-11-20
  • 刊出日期:  2024-04-20

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