RizaSyed Ali, 旭日干, 刘琦, HassanMuhammad, 杨强, 穆道斌, 李丽, 吴锋, 陈人杰. 钠离子电池负极材料综述[J]. 新型炭材料. DOI: 10.1016/S1872-5805(24)60886-3
引用本文: RizaSyed Ali, 旭日干, 刘琦, HassanMuhammad, 杨强, 穆道斌, 李丽, 吴锋, 陈人杰. 钠离子电池负极材料综述[J]. 新型炭材料. DOI: 10.1016/S1872-5805(24)60886-3
Riza Syed Ali, XU Ri-gan, LIU Qi, Hassan Muhammad, YANG Qiang, MU Dao-bin, LI Li, WU Feng, CHEN Ren-jie. A review of anode materials for sodium ion batteries[J]. New Carbon Mater.. DOI: 10.1016/S1872-5805(24)60886-3
Citation: Riza Syed Ali, XU Ri-gan, LIU Qi, Hassan Muhammad, YANG Qiang, MU Dao-bin, LI Li, WU Feng, CHEN Ren-jie. A review of anode materials for sodium ion batteries[J]. New Carbon Mater.. DOI: 10.1016/S1872-5805(24)60886-3

钠离子电池负极材料综述

A review of anode materials for sodium ion batteries

  • 摘要: 锂离子电池在电动车和便携式智能设备中已广泛应用,但其资源日渐枯竭,并且需求不断上升,亟需满足。钠离子电池因其成本较低,且钠元素在自然界中储量丰富,成为替代或补充LIBs的有前景的候选者,并且可应用在大规模储能中。钠离子电池负极材料是电池的重要组成部分,但与正极相比,关于负极的研究相对较少,且仍存在瓶颈。本综述全面讨论了各种基于碳的负极、金属化合物负极和有机负极的研究进展,涉及插层、合金化和转化等不同反应机制,以深入揭示其前景与挑战。讨论了结构改性、纳米结构、掺杂、涂层和固态电解质界面改性等策略,这些策略对钠离子电池负极的电化学性能具有显著影响。还需深入理解钠化机制,以增强钠化和去钠过程中的氧化还原反应动力学。开发经济环保的负极材料,合成具有商业可行性、高初始库伦效率和优良电化学性能的材料,是推动钠离子电池负极材料商业化的必要条件。

     

    Abstract: Lithium-ion batteries (LIBs) are commercially available in electric vehicles and portable smart devices, but the resources are dwindling and there is a rising demand which must be catered. Sodium ion batteries (SIBs) are inexpensive and promising candidates for replacing LIBs in the future, thanks to the abundant reserves of Na element in the nature for large-scale energy storage. Anodes of SIBs, despite being necessary components of batteries, are a bottleneck and less understood compared to the cathode. Herein, a comprehensive study encompassing the progress of various types of carbon-based, metallic compounds and organic anodes by intercalation, alloying and conversion reaction mechanisms is presented to reveal the prospects and challenges in depth. The structural modification and nano-structural, doping, coating, and solid electrolyte interface (SEI) modification strategies which have a good impact on the electrochemical performance of the anodes of SIBs are discussed. The sodiation mechanism should also be understood in depth to enhance the kinetics of the redox reactions during the sodiation and desodiation process. The economical and environmentally friendly anodes that are not only commercially viable, but also have higher initial coulombic efficiency and electrochemical performance are necessary to promote the commercialization of the SIBs anode materials.

     

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