前驱体对炭泡沫孔结构的影响(英文)

Carbon foams were prepared from coal tar pitch, petroleum mesophase pitch, and AR pitch. The molecular weights of the precursors were determined by gel permeation chromatography. Foam structure, average pore diameter and pore diameter distribution were investigated by scanning electron and optical microscopy. It was found that coal tar pitch could not be used as-received to prepare useful carbon foams because of their higher quinoline insoluble (QI) fraction. The carbon foams with homogeneous open pores and microscopic domains were obtained from AR pitch and petroleum mesophase pitch. Carbon foams prepared from AR pitch exhibited a smaller average pore diameter (212μm), thinner cell walls, a narrower pore diameter distribution (180-300μm), higher opencell ratio, and better ligaments compared with those from the other pitches. It is concluded that a precursor with low molecular weight, narrow molecular weight distribution, and low QI content is favorable for the preparation of carbon foams.