One-pot modified “grafting-welding” preparation of graphene/ polyimide carbon films for superior thermal management

LI Hao-liang; WU Xian; CHENG Kui; ZHU Mo-han; WANG Liu-si; YU Hong-liu; YANG Jun-he

doi:10.1016/S1872-5805(21)60076-8

Volume 36 Issue 5

Sep. 2021

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Article Navigation > New Carbon Mater. > 2021 > 36(5): 949-960

LI Hao-liang, WU Xian, CHENG Kui, ZHU Mo-han, WANG Liu-si, YU Hong-liu, YANG Jun-he. One-pot modified “grafting-welding” preparation of graphene/ polyimide carbon films for superior thermal management. New Carbon Mater., 2021, 36(5): 949-960. doi: 10.1016/S1872-5805(21)60076-8

Citation:

LI Hao-liang, WU Xian, CHENG Kui, ZHU Mo-han, WANG Liu-si, YU Hong-liu, YANG Jun-he. One-pot modified “grafting-welding” preparation of graphene/ polyimide carbon films for superior thermal management. New Carbon Mater., 2021, 36(5): 949-960. doi: 10.1016/S1872-5805(21)60076-8

Citation:

LI Hao-liang, WU Xian, CHENG Kui, ZHU Mo-han, WANG Liu-si, YU Hong-liu, YANG Jun-he. One-pot modified “grafting-welding” preparation of graphene/ polyimide carbon films for superior thermal management. New Carbon Mater., 2021, 36(5): 949-960. doi: 10.1016/S1872-5805(21)60076-8

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One-pot modified “grafting-welding” preparation of graphene/ polyimide carbon films for superior thermal management

doi: 10.1016/S1872-5805(21)60076-8

LI Hao-liang^{1, 2
,},
WU Xian¹,
CHENG Kui¹,
ZHU Mo-han¹,
WANG Liu-si¹,
YU Hong-liu²,
YANG Jun-he^{1, 3
,
,}

1.
School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
2.
School of Medical Instrument and Food Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
3.
Prytula Igor Collaborate Innovation Center for Diamond, Shanghai Jian Qiao University, Shanghai 201306, China

Funds: The authors are thankful to Shanghai Sailing Program (20YF1432100), Shanghai Scientific and Technological Innovation Project (19JC1410400) and Innovation Program of Shanghai Municipal Education Commission (2019-01-07-00-07-E00015) for their financial supports to this study

More Information

Author Bio:
李昊亮，博士，博士后. E-mail：lihl1989@outlook.com
Corresponding author: YANG Jun-he, Professor. E-mail: jhyang@usst.edu.cn
Received Date: 2020-10-30
Rev Recd Date: 2021-03-22

Available Online: 2021-08-31

Publish Date: 2021-10-01

Abstract

Abstract

Thermal management has attracted much recent attention due to the rapid development of 5G communication and electronic devices. Reduced GO/polyimide carbon (rGO/PI-carbon) films were prepared by a one-pot“grafting-welding” strategy, where GO was first grafted with amino groups using 1,3-bis(4-aminophenoxy) benzene, then polymerized with polyamic acid (PAA) and pyromellitic dianhydride to connect the GO sheets, before carbonization and graphitization. The rGO/PI film with a mass ratio of GO to PAA of 7% exhibits an increase in in-plane thermal conductivity (1 102 W(m·K)⁻¹) of 48.92% compared with the rGO film. It also has a superior bending performance and survives 2 000 bend cycles with a small radius test while suffering an electrical resistance increase of less than 10%. Grafting-welding of rGO with PI carbon produces effective paths for phonon transport between the graphene sheets, reducing phonon scattering, which makes it a candidate for thermal interface materials for heat dissipation.
- Modification of GO,
- In-situ polymerization,
- Polyimide,
- Graphene composite film,
- Thermal dissipating performance

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References(44)

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