Construction of a flexible, integrated rechargeable Li battery based on a coaxial anode with a carbon fiber core encapsulated in FeNiMnO<sub>4</sub> and a nitrogen-doped carbon sheath

ZOU Yi-ming; SUN Chang-chun; LI Shao-wen; BAI Miao; DU Yu-xuan; ZHANG Min; XU Fei; MA Yue

doi:10.1016/S1872-5805(22)60617-6

Volume 37 Issue 5

Oct. 2022

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Article Navigation > New Carbon Mater. > 2022 > 37(5): 944-955

ZOU Yi-ming, SUN Chang-chun, LI Shao-wen, BAI Miao, DU Yu-xuan, ZHANG Min, XU Fei, MA Yue. Construction of a flexible, integrated rechargeable Li battery based on a coaxial anode with a carbon fiber core encapsulated in FeNiMnO4 and a nitrogen-doped carbon sheath. New Carbon Mater., 2022, 37(5): 944-955. doi: 10.1016/S1872-5805(22)60617-6

Citation:

ZOU Yi-ming, SUN Chang-chun, LI Shao-wen, BAI Miao, DU Yu-xuan, ZHANG Min, XU Fei, MA Yue. Construction of a flexible, integrated rechargeable Li battery based on a coaxial anode with a carbon fiber core encapsulated in FeNiMnO₄ and a nitrogen-doped carbon sheath. New Carbon Mater., 2022, 37(5): 944-955. doi: 10.1016/S1872-5805(22)60617-6

Citation:

ZOU Yi-ming, SUN Chang-chun, LI Shao-wen, BAI Miao, DU Yu-xuan, ZHANG Min, XU Fei, MA Yue. Construction of a flexible, integrated rechargeable Li battery based on a coaxial anode with a carbon fiber core encapsulated in FeNiMnO₄ and a nitrogen-doped carbon sheath. New Carbon Mater., 2022, 37(5): 944-955. doi: 10.1016/S1872-5805(22)60617-6

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Construction of a flexible, integrated rechargeable Li battery based on a coaxial anode with a carbon fiber core encapsulated in FeNiMnO₄ and a nitrogen-doped carbon sheath

doi: 10.1016/S1872-5805(22)60617-6

ZOU Yi-ming^1
,,
SUN Chang-chun²,
LI Shao-wen²,
BAI Miao²,
DU Yu-xuan²,
ZHANG Min²,
XU Fei^{2
,
,},
MA Yue^{2
,
,}

1.
International Research Center for Composite and Intelligent Manufacturing Technology, Institute of Chemical Power Sources, School of Science, Xi'an University of Technology, Xi'an 710048, China
2.
State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, China

More Information

Author Bio:
邹一鸣，讲师. E-mail：zouyiming_uu@163.com
Corresponding author: XU Fei, Professor. E-mail: feixu@nwpu.edu.cn; MA Yue, Professor. E-mail: mayue04@nwpu.edu.cn
Received Date: 2022-04-08
Rev Recd Date: 2022-05-27

Available Online: 2022-05-30

Publish Date: 2022-10-01

Abstract

Abstract

A coaxial anode with a carbon fiber core encapsulated in nanocrystalline FeNiMnO₄ with a nitrogen-doped carbon sheath was prepared using carbon fiber cloth as the core, FeNiMnO₄ nanocrystallite arrays as the first coating layer and nitrogen-doped carbon derived from F127 (a kind of triblock copolymer)-resorcinol-melamine gel as the outer layer. After annealing at 600 °C it was used as the anode material of an all solid flexible lithium ion battery using LiFePO₄ as the cathode material and boron nitride modified polyethylene oxide as the electrolyte. The battery had a large areal capacity of ~1.40 mAh cm⁻² and satisfactory cycling stability under different bending and strain states. Annealing below 600 °C leads to incomplete carbonization of the nitrogen-doped carbon and thus a low electrical conductivity while above 600 °C aggregation of FeNiMnO₄ nanocrystallites and their detachment during cycling are observed under bending and strain.
- Flexible solid-state lithium battery,
- Quaternary oxide,
- Integrated configuration,
- Mechanical flexibility,
- Coaxial structure

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References(27)

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