Research progress on fibrous carbon materials as anode materials for lithium ion batteries
-
摘要: 纤维状炭材料有各种尺度和形貌,由于成本和性能缺乏竞争力,制约其在锂离子电池负极材料中的应用。随着纳米技术的发展,一些改性后的新型炭纤维表现出良好的负极材料性能。文章综述了近年各种纤维状炭材料用作锂离子电池负极材料的国内外研究进展。依据纤维状炭材料的结构、性能及其研究思路,分别归纳了石墨纤维、炭纤维及具有各种微观结构的炭纳米纤维作为负极材料的电化学性能及应用前景。结果表明,纤维状炭材料作为锂离子电池负极材料的研究,经历了从石墨化炭纤维到非石墨化炭纤维,从微米级直径到纳米级直径,从注重研究工艺参数到注重研究和设计微观结构的过程。从提高容量和倍率性能的潜力及成本和可工业化角度考虑,纤维状炭材料极有可能是未来炭负极材料的重要选择。Abstract: Fibrous carbon materials have a variety of dimensions and structures. However, these materials were earlier restricted for use as anode materials for lithium ion batteries due to their cost and performance. With the development of nanotechnology, some modified and new forms of carbon fibers have emerged, which show good performance as anode materials. This paper reviews recent domestic and foreign research progress on fibrous carbon materials as anode materials. The electrochemical performance and prospective use of graphite fibers, carbon fibers and carbon nanofibers for this purpose are summarized. Research has ranged from non-graphitized to graphitized carbon fibers, from micron to nanometer diameter, and has focused on the parameters of their preparation to the design of their microstructure. Fibrous carbon materials are likely to be important alternatives for carbon anode materials in the future based on their high capacity, high rate capability, low cost and ease of industrialization.
-
Key words:
- Fibrous carbon materials /
- Lithium ion battery /
- Anode /
- Application
-
Dai L, Chang D W, Baek J B, et al. Carbon nanomaterials for advanced energy conversion and storage
[J]. Small, 2012, 8(8): 1130-1166.
Yoshino A. The birth of the lithium-ion battery
[J]. Angewandte Chemie-International Edition, 2012, 51(24): 5798-5800.
Liu X M, Huang Z D, Oh S W, et al. Carbon nanotube (CNT)-based composites as electrode material for rechargeable Li-ion batteries: A review
[J]. Composites Science and Technology, 2012, 72(2): 121-144.
Imanishi N, Kashiwagi H, Ichikawa T, et al. Charge-discharge characteristics of mesophase-pitch-based carbon-fibers for lithium cells
[J]. Journal of the Electrochemical Society, 1993, 140(2): 315-320.
Morita M, Nishimura N, Matsuda Y. Charge discharge cycling behavior of pitch-based carbon-fiber in organic electrolyte-solutions
[J]. Electrochimica Acta, 1993, 38(13): 1721-1726.
Takami N, Satoh A, Hara M, et al. Structural and kinetic characterization of lithium intercalation into carbon anodes for secondary lithium batteries
[J]. Journal of the Electrochemical Society, 1995, 142(2): 371-379.
Takami N, Satoh A, Hara M, et al. Rechargeable lithium-ion cells using graphitized mesophase-pitch-based carbon-fiber anodes
[J]. Journal of the Electrochemical Society, 1995, 142(8): 2564-2571.
Takami N, Satoh A, Ohsaki T. Rechargeable lithium-ion cells using a graphitised carbon fibre as anode material
[C]. Power Sources 15. Research and Development in Non-Mechanical Electrical Power Sources, The 19th International Power Sources Symposium, 1995.
Tamaki T. Characteristics of mesophase pitch-based carbon fibers as anode materials for lithium secondary cells
[C]. Materials for Electrochemical Energy Storage and Conversion-Batteries, Capacitors and Fuel Cells, Symposium, 1995.
Ohsaki T, Kanda M, Aoki Y, et al. High-capacity lithium-ion cells using graphitized mesophase-pitch-based carbon fiber anodes
[J]. Journal of Power Sources, 1997, 68(1): 102-105.
Ohsaki T, Takami N, Satoh A, et al. High capacity lithium-ion batteries using graphitized mesophase-pitch-based carbon fiber anodes
[J]. Proceedings of the Symposium on Lithium Polymer Batteries, 1997, 1(68): 102-105.
Endo M, Kim C, Karaki T, et al. Anode performance of a Li-ion battery based on graphitized and B-doped milled mesophase pitch-based carbon fibers
[J]. Carbon, 1999, 37(4): 561-568.
Morita T, Takami N. Characterization of oxidized boron-doped carbon fiber anodes for Li-ion batteries by analysis of heat of immersion
[J]. Electrochimica Acta, 2004, 49(16): 2591-2599.
Suzuki K, Iijima T, Wakihara M. Electrode characteristics of pitch-based carbon fiber as an anode in lithium rechargeable battery
[J]. Electrochimica Acta, 1999, 44(13): 2185-2191.
Takamura T, Suzuki J, Yamada C, et al. Metal film deposition on carbon anodes for high rate charge-discharge of Li-ion batteries
[J]. Surface Engineering, 1999, 15(3): 225-229.
Abe H, Zaghib K, Tatsumi K, et al. Performance of lithium-ion rechargeable batteries-graphite whisker electrolyte LiCoO2 rocking-chair system
[J]. Journal of Power Sources, 1995, 54(2): 236-239.
Tatsumi K, Zaghib K, Sawada Y, et al. Anode performance of vapor-grown carbon-fibers in secondary lithium-ion batteries
[J]. Journal of the Electrochemical Society, 1995, 142(4): 1090-1096.
Endo M, Nishimura Y, Takahashi T, et al. Lithium storage behavior for various kinds of carbon anodes in Li-ion secondary battery
[J]. Journal of Physics and Chemistry of Solids, 1996, 57(6-8): 725-728.
Abe H, Murai T, Zaghib K. Vapor-grown carbon fiber anode for cylindrical lithium ion rechargeable batteries
[J]. Journal of Power Sources, 1999, 77(2): 110-115.
Yoon S H, Park C W, Yang H J, et al. Novel carbon nanofibers of high graphitization as anodic materials for lithium ion secondary batteries
[J]. Carbon, 2004, 42(1): 21-32.
Camean I, Garcia A B, Suelves I, et al. Graphitized carbon nanofibers for use as anodes in lithium-ion batteries: Importance of textural and structural properties
[J]. Journal of Power Sources, 2012, 198: 303-307.
Endo M, Kim Y A, Hayashi T, et al. Vapor-grown carbon fibers (VGCFs)-basic properties and their battery applications
[J]. Carbon, 2001, 39(9): 1287-1297.
Roh Y B, Jeong K M, Cho H G, et al. Unique charge/discharge properties of carbon materials with different structures
[J]. Journal of Power Sources, 1997, 68(2): 271-276.
Tatsumi K, Kawamura T, Higuchi S, et al. Anode characteristics of non-graphitizable carbon fibers for rechargeable lithium-ion batteries
[J]. Journal of Power Sources, 1997, 68(2): 263-266.
Yoon S, Ryu J H, Oh S M, et al. A preparation of carbon fibers using a block copolymer surfactant template and its application to anode of lithium ion batteries
[J]. Journal of Non-Crystalline Solids, 2009, 355(14-15): 913-915.
Lee J K, An K W, Ju J B, et al. Electrochemical properties of pan-based carbon fibers as anodes for rechargeable lithium ion batteries
[J]. Carbon, 2001, 39(9): 1299-1305.
Skowronski J M, Blazewicz S, Knofczynski K. Reversible insertion of lithium ions into carbon/carbon nanocomposite
[J]. Synthetic Metals, 2003, 135(1-3): 733-734.
Nadeau G, Song X Y, Masse M, et al. Effect of heat-treatment and additives on the particles and carbon fibers as anodes for lithium-ion batteries
[J]. Journal of Power Sources, 2002, 108(1-2): 86-96.
Takamura T, Eguchi S, Suzuki J, et al. Impedance measurements of low temperature mesophase carbon fibers during lithium insertion/extraction
[J]. Journal of Power Sources, 2005, 146(1-2): 129-133.
Jang S M, Miyawaki J, Tsuji M, et al. Preparation of a carbon nanofiber/natural graphite composite and an evaluation of its electrochemical properties as an anode material for a Li-ion battery
[J]. New Carbon Materials, 2010, 25(2): 89-96.
Ortiz G F, Alcantara R, Lavela P, et al. Optimization of the electrochemical behavior of vapor grown carbon nanofibers for lithium-ion batteries by impregnation, and thermal and hydrothermal treatments
[J]. Journal of the Electrochemical Society, 2005, 152(9): 1797-1803.
Subramanian V, Zhu H W, Wei B Q. High rate reversibility anode materials of lithium batteries from vapor-grown carbon nanofibers
[J]. Journal of Physical Chemistry B, 2006, 110(14): 7178-7183.
Kim C, Yang K S, Kojima M, et al. Fabrication of electrospinning-derived carbon nanofiber webs for the anode material of lithium-ion secondary batteries
[J]. Advanced Functional Materials, 2006, 16(18): 2393-2397.
Chan K, Young J, Bui T, et al. Synthesis and characterization of porous carbon nanofibers with hollow cores through the thermal treatment of electrospun copolymeric nanofiber webs
[J]. Small, 2007, 3(1): 91-95.
Ji L, Zhang X. Fabrication of porous carbon nanofibers and their application as anode materials for rechargeable lithium-ion batteries
[J]. Nanotechnology, 2009, 20(15): 155705-155712.
Ji L, Lin Z, Medford A J, et al. Porous carbon nanofibers from electrospun polyacrylonitrile/SiO2 composites as an energy storage material
[J]. Carbon, 2009, 47(14): 3346-3354.
Ji L, Yao Y, Toprakci O, et al. Fabrication of carbon nanofiber-driven electrodes from electrospun polyacrylonitrile/polypyrrole bicomponents for high-performance rechargeable lithium-ion batteries
[J]. Journal of Power Sources, 2010, 195(7): 2050-2056.
Zhou H S, Zhu S M, Hibino M, et al. Lithium storage in ordered mesoporous carbon (cmk-3) with high reversible specific energy capacity and good cycling performance
[J]. Advanced Materials, 2003, 15(24): 2107-2111.
Ji L, Zhang X. Generation of activated carbon nanofibers from electrospun polyacrylonitrile-zinc chloride composites for use as anodes in lithium-ion batteries
[J]. Electrochemistry Communications, 2009, 11(3): 684-687.
Nan D, Wang J G, Huang Z H, et al. Highly porous carbon nanofibers from electrospun polyimide/SiO2 hybrids as an improved anode for lithium-ion batteries
[J]. Electrochemistry Communications, 2013, 34: 52-55.
Li C, Yin X, Chen L, et al. Porous carbon nanofibers derived from conducting polymer: Synthesis and application in lithium-ion batteries with high-rate capability
[J]. Journal of Physical Chemistry C, 2009, 113(30): 13438-13442.
Wu X L, Chen L L, Xin S, et al. Preparation and Li storage properties of hierarchical porous carbon fibers derived from alginic acid
[J]. Chemsuschem, 2010, 3(6): 703-707.
Qie L, Chen W M, Wang Z H, et al. Nitrogen-doped porous carbon nanofiber webs as anodes for lithium ion batteries with a superhigh capacity and rate capability
[J]. Advanced materials, 2012, 24(15): 2047-2050.
Bulusheva L G, Okotrub A V, Kurenya A G, et al. Electrochemical properties of nitrogen-doped carbon nanotube anode in Li-ion batteries
[J]. Carbon, 2011, 49(12): 4013-4023.
Rodriguez E, Camean I, Garcia R, et al. Graphitized boron-doped carbon foams: Performance as anodes in lithium-ion batteries
[J]. Electrochimica Acta, 2011, 56(14): 5090-5094.
Su F, Poh C K, Chen J S, et al. Nitrogen-containing microporous carbon nanospheres with improved capacitive properties
[J]. Energy & Environmental Science, 2011, 4(3): 717-724.
Wu G, Dai C, Wang D, et al. Nitrogen-doped magnetic onion-like carbon as support for Pt particles in a hybrid cathode catalyst for fuel cells
[J]. Journal of Materials Chemistry, 2010, 20(15): 3059-3068.
Wu Z S, Ren W, Xu L, et al. Doped graphene sheets as anode materials with superhigh rate and large capacity for lithium ion batteries
[J]. ACS Nano, 2011, 5(7): 5463-5471.
Ohzawa Y, Suzuki T, Achiha T, et al. Surface-modification of anode carbon for lithium-ion battery using chemical vapor infiltration technique
[J]. Journal of Physics and Chemistry of Solids, 2010, 71(4): 654-657.
Liu B, Yu Y, Chang J, et al. An enhanced stable-structure core-shell coaxial carbon nanofiber web as a direct anode material for lithium-based batteries
[J]. Electrochemistry Communications, 2011, 13(6): 558-561.
Skowronski J M, Knofczynski K, Yamada Y. Mechanism of lithium insertion in hollow carbon fibers-based anode
[J]. Solid State Ionics, 2003, 157(1-4): 133-138.
Adelhelm P, Hu Y S, Antonietti M, et al. Hollow Fe-containing carbon fibers with tubular tertiary structure: Preparation and Li-storage properties
[J]. Journal of Materials Chemistry, 2009, 19(11): 1616-1620.
Byoung S L, Seoung B S, Kyu M P, et al. Anodic properties of hollow carbon nanofibers for Li-ion battery
[J]. Journal of Power Sources, 2012, 199: 53-60.
Kaskhedikar N A, Maier J. Lithium storage in carbon nanostructures
[J]. Advanced Materials, 2009, 21: 2664-2680.
Vu A, Qian Y, Stein A. Porous electrode materials for lithium-ion batteries-how to prepare them and what makes them special
[J]. Advanced Energy Materials, 2012, 2(9): 1056-1085.
Mao Y, Duan H, Xu B, et al. Lithium storage in nitrogen-rich mesoporous carbon materials
[J]. Energy & Environmental Science, 2012, 5(7): 7950-7955.
点击查看大图
计量
- 文章访问数: 964
- HTML全文浏览量: 90
- PDF下载量: 1469
- 被引次数: 0